Solvent-induced supramolecular isomers, structural diversity, and unprecedented in situ formation of both inorganic and organic ions in inorganic-organic mercury(II) complexes.

نویسندگان

  • Zi-Zun Yuan
  • Feng Luo
  • Yu-mei Song
  • Gong-ming Sun
  • Xiao-zhao Tian
  • Hai-xiao Huang
  • Yan Zhu
  • Xue-feng Feng
  • Ming-biao Luo
  • Shu-juan Liu
  • Wen-yuan Xu
چکیده

Reported here is, for the first time, an important study of solvent effect on structural diversity in inorganic-organic mercury(II) complexes. As a result, the first supramolecular isomer in mercury(II) complexes is obtained. Importantly, a previously unobserved in situ generation of both inorganic (Cl(-)) and organic ([CH(3)-L1-CH(3)](2+)) ions was also observed.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Sonochemical Synthesis of Novel Nano Flower Lead(II) Metal-organic Coordination Polymer: A New Precursor to Produce Nano-sized PbO

Metal-organic coordination polymers are a class of organic–inorganic materials consists of metal ions linked together through multi-dentate organic ligands, to form a polymeric chain. These materials have received a great deal of attention in a wide range of different areassuch as catalysis, sensing, luminescence, separation and storage used . The new nano flowerPb(II) 1Dmetal-organic chain {[P...

متن کامل

Surface-grafted Europium and Erbium Complexes of the 12-Tungstosilicate Heteropolyoxometalate: A Synthetic and Structural Investigations

The hydrothermal synthesis of two new inorganic-organic hybrid materials in which PDA (PDA = 1,10-phenanthroline-2,9-dicarboxylate) is connected to a well-defined Keggin-type polyoxometalate anion (POM) and a Ln(III) cation (POM = [SiW12O40]4−; Ln = Eu3+ (1), Er3+ (2)), are reported. These hybrids are characterized by elemental analyses, IR spectra and single-crystal X-ray diffraction. Single-c...

متن کامل

Synthesis of graphene oxide-Melamine – TioOxalic acid nanocomposite and its application in the elimination of Mercury (II) ions

In this study a new method by Application of graphene oxide Nano sheets– Melamine –TioOxalic acid composite was exhibited as adsorbent for the elimination of toxic mercury (II) ions from aqueous solutions. The combine has the authority to adsorb the organic and inorganic combines. Through the immobilization of Melamine-TioOxalic acid (MTO) onto graphene oxide nanosheets, the desired composite w...

متن کامل

Solvatochromic Properties of Heteroleptic Copper(II) Complexes Containing N,N,N',N'-Tetramethylethylenediamine and 2-Aacetylcyclopentanone Ligands

Three new heteroleptic copper(II) complexes, [(tmen)Cu(dike)H2O]X where tmen = N,N,N',N'-tetramethylethylenediamine, dike = 2-acetylcyclopentanone anion and X= ClO4- (1), Cl- (2) and Br- (3) are prepared and characterized by elemental analyses, molar conductance measurements and IR and UV-Vis spectroscopy techniques. The complex 1 is fairly soluble in various organic solvents and demonstrates d...

متن کامل

Heavy metals removal from wastewater by using different kinds of magnetite nanoadsorbents: effects of different organic and inorganic coatings on the removal of copper and lead ions

Co-precipitation procedure was applied in order to obtain different kinds of magnetic nanoadsobents for the removal of Pb(II) and Cu(II) toxic metal ions from wastewater samples. Prepared nanoadsorbents were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometer (XRD), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). The average sizes of t...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Dalton transactions

دوره 41 41  شماره 

صفحات  -

تاریخ انتشار 2012